Synthesis and structural characterization of a [Ag4]4+ cluster stabilized by a mixed-donor N-heterocyclic carbene linked cyclophane and the first reported synthesis of a N-heterocyclic carbene complex in water

Jered C. Garrison; Richard S. Simons; Claire A. Tessier; Wiley J. Youngs

doi:10.1016/S0022-328X(03)00151-7

Synthesis and structural characterization of a [Ag4]⁴⁺ cluster stabilized by a mixed-donor N-heterocyclic carbene linked cyclophane and the first reported synthesis of a N-heterocyclic carbene complex in water

Jered C. Garrison, Richard S. Simons, Claire A. Tessier, Wiley J. Youngs

Research output: Contribution to journal › Article › peer-review

101 Scopus citations

Abstract

The synthesis of the tetranuclear Ag₄⁴⁺ cluster stabilized by a N-heterocyclic carbene macrocycle (3)[PF₆]₄. Decomposition of the tetranuclear cluster (3)[PF₆]₄ in light forms the dimeric species (2)[PF₆]₂. In situ synthesis of the dimeric silver N-hetrocyclic carbene complex (2)[Br]₂ in water.

Original language	English (US)
Pages (from-to)	1-4
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	673
Issue number	1-2
DOIs	https://doi.org/10.1016/S0022-328X(03)00151-7
State	Published - Apr 30 2003
Externally published	Yes

Keywords

N-heterocyclic carbene
Silver carbene
Silver cluster
X-ray structures

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0022-328X(03)00151-7

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Garrison, J. C., Simons, R. S., Tessier, C. A., & Youngs, W. J. (2003). Synthesis and structural characterization of a [Ag4]⁴⁺ cluster stabilized by a mixed-donor N-heterocyclic carbene linked cyclophane and the first reported synthesis of a N-heterocyclic carbene complex in water. Journal of Organometallic Chemistry, 673(1-2), 1-4. https://doi.org/10.1016/S0022-328X(03)00151-7

Synthesis and structural characterization of a [Ag4]⁴⁺ cluster stabilized by a mixed-donor N-heterocyclic carbene linked cyclophane and the first reported synthesis of a N-heterocyclic carbene complex in water. / Garrison, Jered C.; Simons, Richard S.; Tessier, Claire A. et al.
In: Journal of Organometallic Chemistry, Vol. 673, No. 1-2, 30.04.2003, p. 1-4.

Research output: Contribution to journal › Article › peer-review

Garrison, JC, Simons, RS, Tessier, CA & Youngs, WJ 2003, 'Synthesis and structural characterization of a [Ag4]⁴⁺ cluster stabilized by a mixed-donor N-heterocyclic carbene linked cyclophane and the first reported synthesis of a N-heterocyclic carbene complex in water', Journal of Organometallic Chemistry, vol. 673, no. 1-2, pp. 1-4. https://doi.org/10.1016/S0022-328X(03)00151-7

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title = "Synthesis and structural characterization of a [Ag4]4+ cluster stabilized by a mixed-donor N-heterocyclic carbene linked cyclophane and the first reported synthesis of a N-heterocyclic carbene complex in water",

abstract = "The synthesis of the tetranuclear Ag44+ cluster stabilized by a N-heterocyclic carbene macrocycle (3)[PF6]4. Decomposition of the tetranuclear cluster (3)[PF6]4 in light forms the dimeric species (2)[PF6]2. In situ synthesis of the dimeric silver N-hetrocyclic carbene complex (2)[Br]2 in water.",

keywords = "N-heterocyclic carbene, Silver carbene, Silver cluster, X-ray structures",

author = "Garrison, {Jered C.} and Simons, {Richard S.} and Tessier, {Claire A.} and Youngs, {Wiley J.}",

note = "Funding Information: JCG is grateful for a fellowship from Flexsys America. This work was also supported by an award given by the American Heart Association. We would like to thank the University of Akron and the Ohio Board of Reagents for financial support. We wish to thank Dr Judith Gallucci for assistance in the collection of X-ray diffraction data for [ 3 ][PF 6 ] 4 .",

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AU - Garrison, Jered C.

AU - Simons, Richard S.

AU - Tessier, Claire A.

AU - Youngs, Wiley J.

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KW - X-ray structures

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