Synthesis of oxazolidinone and tosyl enamines by tertiary amine catalysis

Nicholas A. Eddy, Peter D. Morse, Martha D. Morton, Gabriel Fenteany

Research output: Contribution to journalArticle

3 Scopus citations

Abstract

A procedure for the synthesis of oxazolidinone and tosyl enamines is reported. Alkynoyl oxazolidinones and tosyl imides undergo reaction to form enamines in the presence of catalytic amounts of tertiary amines. The data suggest that an amide anion is formed during the reaction, which undergoes conjugate addition to form the final product.

Original languageEnglish (US)
Article numberS09110ST
Pages (from-to)699-701
Number of pages3
JournalSynlett
Issue number5
DOIs
StatePublished - Feb 24 2011

Keywords

  • catalysis
  • enamine
  • oxazolidinone
  • tosyl imide

ASJC Scopus subject areas

  • Organic Chemistry

Fingerprint Dive into the research topics of 'Synthesis of oxazolidinone and tosyl enamines by tertiary amine catalysis'. Together they form a unique fingerprint.

  • Cite this