Abstract
A surprisingly large stereodirecting effect for the allylic alkoxy-substituent (> 4 kcal/mol) is revealed in the amidomercuration cyclization of an unsaturated amidal in which the stereodirecting effect of the allylic alkoxy-substituent competes against the stcreodirecting effect of a stereogenic amidal center.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 6765-6768 |
| Number of pages | 4 |
| Journal | Tetrahedron Letters |
| Volume | 31 |
| Issue number | 47 |
| DOIs | |
| State | Published - 1990 |
ASJC Scopus subject areas
- Biochemistry
- Drug Discovery
- Organic Chemistry
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Takacs, J. M., Helle, M. A., Sanyal, B. J., & Eberspacher, T. A. (1990). The magnitude of the stereodirecting effect of an allylic alkoxy-substituent in an amidomercuration cyclization. Tetrahedron Letters, 31(47), 6765-6768. https://doi.org/10.1016/S0040-4039(00)97166-1