The nuclear hexadecapole interaction of iodine-127 in cadmium iodide measured using zero-field two dimensional nuclear magnetic resonance

Ming Yuan Liao; Gerard S. Harbison

doi:10.1063/1.466542

The nuclear hexadecapole interaction of iodine-127 in cadmium iodide measured using zero-field two dimensional nuclear magnetic resonance

Ming Yuan Liao, Gerard S. Harbison

Chemistry

Research output: Contribution to journal › Article

15 Scopus citations

Abstract

Two dimensional nuclear quadrupole correlation spectroscopy has been used to measure simultaneously the two nuclear spin transition frequencies for the iodine resonance of cadmium iodide at zero magnetic field. Because of the layer structure and resultant polymorphism in this substance, conventional zero-field NMR spectra are inhomogeneously broadened by several hundred kHz. However, the, 2D spectra obtained by our method are subject only to homogeneous linewidth, which for this compound is of the order of 5 kHz. This greatly increased precision allows more accurate evaluation of the nuclear hexadecapole coupling in cadmium iodide; which we measure as 0.216±0.514 kHz (i.e., indistinguishable from zero). This gives a maximum value of the nuclear hexadecapole moment several times lower than that recently reported for the same nucleus in potassium iodide.

Original language	English (US)
Pages (from-to)	1895-1901
Number of pages	7
Journal	The Journal of Chemical Physics
Volume	100
Issue number	3
DOIs	https://doi.org/10.1063/1.466542
State	Published - 1994

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

Access to Document

10.1063/1.466542

Fingerprint Dive into the research topics of 'The nuclear hexadecapole interaction of iodine-127 in cadmium iodide measured using zero-field two dimensional nuclear magnetic resonance'. Together they form a unique fingerprint.

Cite this

Liao, M. Y., & Harbison, G. S. (1994). The nuclear hexadecapole interaction of iodine-127 in cadmium iodide measured using zero-field two dimensional nuclear magnetic resonance. The Journal of Chemical Physics, 100(3), 1895-1901. https://doi.org/10.1063/1.466542

@article{9655623b2a9745b58b1ad5d6f8fc5694,

title = "The nuclear hexadecapole interaction of iodine-127 in cadmium iodide measured using zero-field two dimensional nuclear magnetic resonance",

abstract = "Two dimensional nuclear quadrupole correlation spectroscopy has been used to measure simultaneously the two nuclear spin transition frequencies for the iodine resonance of cadmium iodide at zero magnetic field. Because of the layer structure and resultant polymorphism in this substance, conventional zero-field NMR spectra are inhomogeneously broadened by several hundred kHz. However, the, 2D spectra obtained by our method are subject only to homogeneous linewidth, which for this compound is of the order of 5 kHz. This greatly increased precision allows more accurate evaluation of the nuclear hexadecapole coupling in cadmium iodide; which we measure as 0.216±0.514 kHz (i.e., indistinguishable from zero). This gives a maximum value of the nuclear hexadecapole moment several times lower than that recently reported for the same nucleus in potassium iodide.",

author = "Liao, {Ming Yuan} and Harbison, {Gerard S.}",

year = "1994",

doi = "10.1063/1.466542",

language = "English (US)",

volume = "100",

pages = "1895--1901",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics Publising LLC",

number = "3",

}

TY - JOUR

T1 - The nuclear hexadecapole interaction of iodine-127 in cadmium iodide measured using zero-field two dimensional nuclear magnetic resonance

AU - Liao, Ming Yuan

AU - Harbison, Gerard S.

PY - 1994

Y1 - 1994

N2 - Two dimensional nuclear quadrupole correlation spectroscopy has been used to measure simultaneously the two nuclear spin transition frequencies for the iodine resonance of cadmium iodide at zero magnetic field. Because of the layer structure and resultant polymorphism in this substance, conventional zero-field NMR spectra are inhomogeneously broadened by several hundred kHz. However, the, 2D spectra obtained by our method are subject only to homogeneous linewidth, which for this compound is of the order of 5 kHz. This greatly increased precision allows more accurate evaluation of the nuclear hexadecapole coupling in cadmium iodide; which we measure as 0.216±0.514 kHz (i.e., indistinguishable from zero). This gives a maximum value of the nuclear hexadecapole moment several times lower than that recently reported for the same nucleus in potassium iodide.

AB - Two dimensional nuclear quadrupole correlation spectroscopy has been used to measure simultaneously the two nuclear spin transition frequencies for the iodine resonance of cadmium iodide at zero magnetic field. Because of the layer structure and resultant polymorphism in this substance, conventional zero-field NMR spectra are inhomogeneously broadened by several hundred kHz. However, the, 2D spectra obtained by our method are subject only to homogeneous linewidth, which for this compound is of the order of 5 kHz. This greatly increased precision allows more accurate evaluation of the nuclear hexadecapole coupling in cadmium iodide; which we measure as 0.216±0.514 kHz (i.e., indistinguishable from zero). This gives a maximum value of the nuclear hexadecapole moment several times lower than that recently reported for the same nucleus in potassium iodide.

UR - http://www.scopus.com/inward/record.url?scp=36449005024&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=36449005024&partnerID=8YFLogxK

U2 - 10.1063/1.466542

DO - 10.1063/1.466542

M3 - Article

AN - SCOPUS:36449005024

VL - 100

SP - 1895

EP - 1901

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 3

ER -