The potential use of rhodium N-heterocyclic carbene complexes as radiopharmaceuticals: The transfer of a carbene from Ag(I) to RhCl 3·3H 2O

Carol A. Quezada; Jered C. Garrison; Matthew J. Panzner; Claire A. Tessier; Wiley J. Youngs

doi:10.1021/om049697d

The potential use of rhodium N-heterocyclic carbene complexes as radiopharmaceuticals: The transfer of a carbene from Ag(I) to RhCl ₃·3H ₂O

Carol A. Quezada, Jered C. Garrison, Matthew J. Panzner, Claire A. Tessier, Wiley J. Youngs

Research output: Contribution to journal › Article › peer-review

84 Scopus citations

Abstract

In order to use radioactive rhodium N-heterocyclic carbene (Rh NHC) complexes for possible cancer therapy, it is required to start with RhCl ₃·xH ₂O, a synthesis not previously accomplished. We have successfully synthesized and characterized two new Rh (NHC) complexes starting from RhCl ₃·xH ₂O via a silver transfer mechanism.

Original language	English (US)
Pages (from-to)	4846-4848
Number of pages	3
Journal	Organometallics
Volume	23
Issue number	21
DOIs	https://doi.org/10.1021/om049697d
State	Published - Oct 11 2004
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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The potential use of rhodium N-heterocyclic carbene complexes as radiopharmaceuticals : The transfer of a carbene from Ag(I) to RhCl ₃·3H ₂O. / Quezada, Carol A.; Garrison, Jered C.; Panzner, Matthew J.; Tessier, Claire A.; Youngs, Wiley J.

In: Organometallics, Vol. 23, No. 21, 11.10.2004, p. 4846-4848.

Research output: Contribution to journal › Article › peer-review

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abstract = "In order to use radioactive rhodium N-heterocyclic carbene (Rh NHC) complexes for possible cancer therapy, it is required to start with RhCl 3·xH 2O, a synthesis not previously accomplished. We have successfully synthesized and characterized two new Rh (NHC) complexes starting from RhCl 3·xH 2O via a silver transfer mechanism.",

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AU - Youngs, Wiley J.

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AB - In order to use radioactive rhodium N-heterocyclic carbene (Rh NHC) complexes for possible cancer therapy, it is required to start with RhCl 3·xH 2O, a synthesis not previously accomplished. We have successfully synthesized and characterized two new Rh (NHC) complexes starting from RhCl 3·xH 2O via a silver transfer mechanism.

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The potential use of rhodium N-heterocyclic carbene complexes as radiopharmaceuticals: The transfer of a carbene from Ag(I) to RhCl ₃·3H ₂O

Abstract

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