The potential use of rhodium N-heterocyclic carbene complexes as radiopharmaceuticals: The transfer of a carbene from Ag(I) to RhCl 3·3H 2O

Carol A. Quezada; Jered C. Garrison; Matthew J. Panzner; Claire A. Tessier; Wiley J. Youngs

doi:10.1021/om049697d

The potential use of rhodium N-heterocyclic carbene complexes as radiopharmaceuticals: The transfer of a carbene from Ag(I) to RhCl ₃·3H ₂O

Carol A. Quezada, Jered C. Garrison, Matthew J. Panzner, Claire A. Tessier, Wiley J. Youngs

Research output: Contribution to journal › Article › peer-review

83 Scopus citations

Abstract

In order to use radioactive rhodium N-heterocyclic carbene (Rh NHC) complexes for possible cancer therapy, it is required to start with RhCl ₃·xH ₂O, a synthesis not previously accomplished. We have successfully synthesized and characterized two new Rh (NHC) complexes starting from RhCl ₃·xH ₂O via a silver transfer mechanism.

Original language	English (US)
Pages (from-to)	4846-4848
Number of pages	3
Journal	Organometallics
Volume	23
Issue number	21
DOIs	https://doi.org/10.1021/om049697d
State	Published - Oct 11 2004
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Access to Document

10.1021/om049697d

Fingerprint Dive into the research topics of 'The potential use of rhodium N-heterocyclic carbene complexes as radiopharmaceuticals: The transfer of a carbene from Ag(I) to RhCl <sub>3</sub>·3H <sub>2</sub>O'. Together they form a unique fingerprint.

Cite this

The potential use of rhodium N-heterocyclic carbene complexes as radiopharmaceuticals : The transfer of a carbene from Ag(I) to RhCl ₃·3H ₂O. / Quezada, Carol A.; Garrison, Jered C.; Panzner, Matthew J.; Tessier, Claire A.; Youngs, Wiley J.

In: Organometallics, Vol. 23, No. 21, 11.10.2004, p. 4846-4848.

Research output: Contribution to journal › Article › peer-review

@article{77e8f7d358fe4018b32edfe7b37d96ed,

title = "The potential use of rhodium N-heterocyclic carbene complexes as radiopharmaceuticals: The transfer of a carbene from Ag(I) to RhCl 3·3H 2O",

abstract = "In order to use radioactive rhodium N-heterocyclic carbene (Rh NHC) complexes for possible cancer therapy, it is required to start with RhCl 3·xH 2O, a synthesis not previously accomplished. We have successfully synthesized and characterized two new Rh (NHC) complexes starting from RhCl 3·xH 2O via a silver transfer mechanism.",

author = "Quezada, {Carol A.} and Garrison, {Jered C.} and Panzner, {Matthew J.} and Tessier, {Claire A.} and Youngs, {Wiley J.}",

year = "2004",

month = oct,

day = "11",

doi = "10.1021/om049697d",

language = "English (US)",

volume = "23",

pages = "4846--4848",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "21",

}

TY - JOUR

T1 - The potential use of rhodium N-heterocyclic carbene complexes as radiopharmaceuticals

T2 - The transfer of a carbene from Ag(I) to RhCl 3·3H 2O

AU - Quezada, Carol A.

AU - Garrison, Jered C.

AU - Panzner, Matthew J.

AU - Tessier, Claire A.

AU - Youngs, Wiley J.

PY - 2004/10/11

Y1 - 2004/10/11

N2 - In order to use radioactive rhodium N-heterocyclic carbene (Rh NHC) complexes for possible cancer therapy, it is required to start with RhCl 3·xH 2O, a synthesis not previously accomplished. We have successfully synthesized and characterized two new Rh (NHC) complexes starting from RhCl 3·xH 2O via a silver transfer mechanism.

AB - In order to use radioactive rhodium N-heterocyclic carbene (Rh NHC) complexes for possible cancer therapy, it is required to start with RhCl 3·xH 2O, a synthesis not previously accomplished. We have successfully synthesized and characterized two new Rh (NHC) complexes starting from RhCl 3·xH 2O via a silver transfer mechanism.

UR - http://www.scopus.com/inward/record.url?scp=6344291932&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=6344291932&partnerID=8YFLogxK

U2 - 10.1021/om049697d

DO - 10.1021/om049697d

M3 - Article

AN - SCOPUS:6344291932

VL - 23

SP - 4846

EP - 4848

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 21

ER -