Water absorption and desorption from the dipole ordered polymer poly(methylvinylidene cyanide)

P. A. Jacobson; Carolina C. Ilie; I. N. Yakovkin; Matt Poulsen; D. Sahadeva Reddy; James M. Takacs; P. A. Dowben

doi:10.1021/jp062699m

Water absorption and desorption from the dipole ordered polymer poly(methylvinylidene cyanide)

P. A. Jacobson, Carolina C. Ilie, I. N. Yakovkin, Matt Poulsen, D. Sahadeva Reddy, James M. Takacs, P. A. Dowben

Chemistry

Research output: Contribution to journal › Article

6 Scopus citations

Abstract

From thermal desorption studies, we find evidence that absorbed water in the bulk of poly(methylvinylidene cyanide) is more weakly bound than is the case for copolymer films of poly(vinylidenefluoride-trifluoroethylene). Ultraviolet laser enhanced thermal desorption of absorbed water exhibits little light polarization dependence for poly(methylvinylidene cyanide) in contrast to absorbed water in copolymer films of poly(vinylidenefluoride-trifluoroethylene). The implications of these differences are discussed.

Original language	English (US)
Pages (from-to)	15389-15392
Number of pages	4
Journal	Journal of Physical Chemistry B
Volume	110
Issue number	31
DOIs	https://doi.org/10.1021/jp062699m
State	Published - Aug 10 2006

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Surfaces, Coatings and Films
Materials Chemistry

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10.1021/jp062699m

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Jacobson, P. A., Ilie, C. C., Yakovkin, I. N., Poulsen, M., Reddy, D. S., Takacs, J. M., & Dowben, P. A. (2006). Water absorption and desorption from the dipole ordered polymer poly(methylvinylidene cyanide). Journal of Physical Chemistry B, 110(31), 15389-15392. https://doi.org/10.1021/jp062699m

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abstract = "From thermal desorption studies, we find evidence that absorbed water in the bulk of poly(methylvinylidene cyanide) is more weakly bound than is the case for copolymer films of poly(vinylidenefluoride-trifluoroethylene). Ultraviolet laser enhanced thermal desorption of absorbed water exhibits little light polarization dependence for poly(methylvinylidene cyanide) in contrast to absorbed water in copolymer films of poly(vinylidenefluoride-trifluoroethylene). The implications of these differences are discussed.",

author = "Jacobson, {P. A.} and Ilie, {Carolina C.} and Yakovkin, {I. N.} and Matt Poulsen and Reddy, {D. Sahadeva} and Takacs, {James M.} and Dowben, {P. A.}",

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T1 - Water absorption and desorption from the dipole ordered polymer poly(methylvinylidene cyanide)

AU - Jacobson, P. A.

AU - Ilie, Carolina C.

AU - Yakovkin, I. N.

AU - Poulsen, Matt

AU - Reddy, D. Sahadeva

AU - Takacs, James M.

AU - Dowben, P. A.

PY - 2006/8/10

Y1 - 2006/8/10

N2 - From thermal desorption studies, we find evidence that absorbed water in the bulk of poly(methylvinylidene cyanide) is more weakly bound than is the case for copolymer films of poly(vinylidenefluoride-trifluoroethylene). Ultraviolet laser enhanced thermal desorption of absorbed water exhibits little light polarization dependence for poly(methylvinylidene cyanide) in contrast to absorbed water in copolymer films of poly(vinylidenefluoride-trifluoroethylene). The implications of these differences are discussed.

AB - From thermal desorption studies, we find evidence that absorbed water in the bulk of poly(methylvinylidene cyanide) is more weakly bound than is the case for copolymer films of poly(vinylidenefluoride-trifluoroethylene). Ultraviolet laser enhanced thermal desorption of absorbed water exhibits little light polarization dependence for poly(methylvinylidene cyanide) in contrast to absorbed water in copolymer films of poly(vinylidenefluoride-trifluoroethylene). The implications of these differences are discussed.

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